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The ‘Adapters and Bindings’ Tab in Windows 10 is no longer available as shown in [How to change network connection priority in Windows 10].

Here’s a workaround so that the network adapter priority can be controlled. In my case I wanted to use Wifi for network connectivity while also connecting to a wired router.

[reference]

1. Goto Control Panel > Network and Internet > Network Connections

2. Right click the desired connection (Higher Priority Connection)

3. Click Properties > Internet Protocol Version 4

4. Click Properties > Advanced

5. Uncheck 'Automatic Metric'

6. Enter 10 in 'Interface Metric'

7. Click OK